Synthesis of new red phosphors with a smart material as a host material
20 Jul 2021
The valence of Mn changes from 4 to 3 under various conditions
Professor Hiromi Nakano of Toyohashi University of Technology used a material with a unique periodical structure (smart material: Li-M-Ti-O [M = Nb or Ta]) as a host material to synthesize new Mn4+-activated phosphors that exhibit red light emissions at 685 nm when excited at 493 nm. Because the valence of the Mn ions in the material changes from Mn4+ to Mn3+ according to the sintering temperature, composition, and crystal structure, there is a difference in the photoluminescence intensity of the phosphors. XRD, TEM, and XANES were used to clarify the relationship between the photoluminescence intensity and the sintering temperature, composition, crystal structure, and MgO co-doping.
Full text: Synthesis of new red phosphors with a smart material as a host material
TUT website: Press release